Major challenges of Fernand Claisse, in the borate fusion technique

1955 Discovery of the borate fusion; presented for the first time at the 1956 Pittsburgh Conference: accurate XRF analysis was impossible on currently used solid powders.

1971 One of the early fusion machines, the Stirrer (Fluxer I) : fusion machines became a must after fusion had became widespread.

1973. The Fluxer VI, a fusion machine with the more efficient mixing ever attained: a very popular machine, discontinued in 1987 for stricter security regulations.

1984 The Fluxer-Bis! and the Bis! crucible (crucible with a hump in the bottom to enhance mixing). The first machine to make both fused beads and solutions: an answer to a new strong competitor in the market.

1988 The Fluxy, an instrument with mixing nearly as efficient as in the Fluxer VI that is still very popular today: the Fluxer-Bis! was not the instrument for the job, it had to be replaced by a better instrument.

1994 The first successful and easy fusion technique for sulphides: the more important industrial sulphide ores of iron, copper, zinc were the only minerals that could not be fused, and laboratories had to rely on slower chemical methods.

1995 A novel method for manufacturing powders of flux at ambient, and a technique for making ultra-clean tiny glass beads of flux: to remove all causes of contamination found in other brands of fluxes.

1997 Discovery of selection rules for the optimal flux composition for each type of samples: many laboratories were rejecting fusion for unexplainable problems.

1999 A new one-step fusion technique for fusing metal powders, including Ferroalloys: the existing methods were unsafe, very complex, slow, and applicable to very small samples only.

2004 The first book on the "Physics and Chemistry of Borate Fusion" : after nearly 50 years of fusion, no research on fusion, except recipes, had been published in the literature, while fusion users needed basic information to intelligently overcome the difficulties to make fusion beads.

2004 A true Sherman Fundamental Parameter software, XRF Direct , particularly useful for the analysis of samples prepared as Fused Beads: softwares based on constant influence coefficients have too limited flexibility to suit all fusion conditions.

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